You can add these missing definitions yourself without much trouble. First locate the Apache mime types table (mime.types) and then just add the following and restart your apache server.
application/vnd.ms-word.document.macroEnabled.12 docm application/vnd.openxmlformats-officedocument.wordprocessingml.document docx application/vnd.openxmlformats-officedocument.wordprocessingml.template dotx application/vnd.ms-powerpoint.template.macroEnabled.12 potm application/vnd.openxmlformats-officedocument.presentationml.template potx application/vnd.ms-powerpoint.addin.macroEnabled.12 ppam application/vnd.ms-powerpoint.slideshow.macroEnabled.12 ppsm application/vnd.openxmlformats-officedocument.presentationml.slideshow ppsx application/vnd.ms-powerpoint.presentation.macroEnabled.12 pptm application/vnd.openxmlformats-officedocument.presentationml.presentation pptx application/vnd.ms-excel.addin.macroEnabled.12 xlam application/vnd.ms-excel.sheet.binary.macroEnabled.12 xlsb application/vnd.ms-excel.sheet.macroEnabled.12 xlsm application/vnd.openxmlformats-officedocument.spreadsheetml.sheet xlsx application/vnd.ms-excel.template.macroEnabled.12 xltm application/vnd.openxmlformats-officedocument.spreadsheetml.template xltx
For MediaWiki to identify the correct mime type (during upload) you can also add the above unmodified to includes/mime.types.
The MediaWiki file includes/mime.info has no practical use currently but you could add the following to it for completeness:
application/vnd.ms-word.document.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.wordprocessingml.document [OFFICE] application/vnd.openxmlformats-officedocument.wordprocessingml.template [OFFICE] application/vnd.ms-powerpoint.template.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.presentationml.template [OFFICE] application/vnd.ms-powerpoint.addin.macroEnabled.12 [OFFICE] application/vnd.ms-powerpoint.slideshow.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.presentationml.slideshow [OFFICE] application/vnd.ms-powerpoint.presentation.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.presentationml.presentation [OFFICE] application/vnd.ms-excel.addin.macroEnabled.12 [OFFICE] application/vnd.ms-excel.sheet.binary.macroEnabled.12 [OFFICE] application/vnd.ms-excel.sheet.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.spreadsheetml.sheet [OFFICE] application/vnd.ms-excel.template.macroEnabled.12 [OFFICE] application/vnd.openxmlformats-officedocument.spreadsheetml.template [OFFICE]
Finally remember to add the file types to the variable $wgFileExtensions in LocalSettings.php.